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Top Articles

#TitleJournalYearCitations
1Reticular synthesis and the design of new materialsNature20038,374
2Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageScience20027,254
3Design and synthesis of an exceptionally stable and highly porous metal-organic frameworkNature19997,021
4Palladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsChemical Reviews20105,643
5Porous, Crystalline, Covalent Organic FrameworksScience20055,574
6Modular Chemistry:  Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate FrameworksAccounts of Chemical Research20014,980
7Hydrogen Storage in Microporous Metal-Organic FrameworksScience20034,435
8A route to high surface area, porosity and inclusion of large molecules in crystalsNature20042,574
9Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room TemperatureJournal of the American Chemical Society20052,573
10Advances in molecular quantum chemistry contained in the Q-Chem 4 program packageMolecular Physics20152,561
11Metal–organic frameworks: a new class of porous materialsMicroporous and Mesoporous Materials20042,520
12Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building UnitsJournal of the American Chemical Society20052,186
13Reticular Chemistry:  Occurrence and Taxonomy of Nets and Grammar for the Design of FrameworksAccounts of Chemical Research20052,072
14Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic FrameworksJournal of the American Chemical Society20061,710
15Percolation and cluster distribution. I. Cluster multiple labeling technique and critical concentration algorithmPhysical Review B19761,673
16Hydrogen Sorption in Functionalized Metal−Organic FrameworksJournal of the American Chemical Society20041,258
17Controlling Site Selectivity in Palladium-Catalyzed C–H Bond FunctionalizationAccounts of Chemical Research20121,257
18Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large PoresScience20011,211
19Exceptional H2Saturation Uptake in Microporous Metal−Organic FrameworksJournal of the American Chemical Society20061,172
20Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V CompoundsJournal of Chemical Physics19601,151
21A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of AlkanesAngewandte Chemie - International Edition20061,128
22A Highly Selective Catalytic Method for the Oxidative Functionalization of C−H BondsJournal of the American Chemical Society2004982
23Nucleophilic Phosphine OrganocatalysisAdvanced Synthesis and Catalysis2004920
24Transition metal catalyzed oxidative functionalization of carbon–hydrogen bondsTetrahedron2006861
25Fractal Reaction KineticsScience1988854
26Molecular robots guided by prescriptive landscapesNature2010843
27Spontaneous assembly of a hinged coordination networkNature1995842
28Gas Adsorption Sites in a Large-Pore Metal-Organic FrameworkScience2005842
29Dimers of mitochondrial ATP synthase form the permeability transition poreProceedings of the National Academy of Sciences of the United States of America2013822
30Photochemical Approaches to Complex Chemotypes: Applications in Natural Product SynthesisChemical Reviews2016792
31Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures▵Journal of the American Chemical Society2001789
32High-valent organometallic copper and palladium in catalysisNature2012740
33Oxidative C−H Activation/C−C Bond Forming Reactions:  Synthetic Scope and Mechanistic InsightsJournal of the American Chemical Society2005739
34Targeted Gold Nanoparticles Enable Molecular CT Imaging of CancerNano Letters2008710
35Palladium-Catalyzed Oxygenation of Unactivated sp3C−H BondsJournal of the American Chemical Society2004682
36Efficiency in Nonenzymatic Kinetic ResolutionAngewandte Chemie - International Edition2005681
37Mesolimbic dopamine signals the value of workNature Neuroscience2016644
38Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building BlocksJournal of the American Chemical Society2001639
39Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3IJournal of the American Chemical Society2012624
40Room Temperature Palladium-Catalyzed 2-Arylation of IndolesJournal of the American Chemical Society2006607
41Fluorescent Fiber-Optic Calcium Sensor for Physiological MeasurementsAnalytical Chemistry1996605
42Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light PhotocatalysisJournal of the American Chemical Society2011597
43Palladium-Catalyzed Fluorination of Carbon−Hydrogen BondsJournal of the American Chemical Society2006580
44Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal PolyhedraJournal of the American Chemical Society2005579
45Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule SynthesisAccounts of Chemical Research2015562
46Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H SubstratesJournal of the American Chemical Society2007558
47Aliphatic hydroxylation by highly purified liver microsomal cytochrome P-450. Evidence for a carbon radical intermediateBiochemical and Biophysical Research Communications1978535
48Solid-State Packing of Conjugated Oligomers:  From π-Stacks to the Herringbone StructureJournal of the American Chemical Society2004529
49Oxygen sensation and social feeding mediated by a C. elegans guanylate cyclase homologueNature2004529
50Cascade Catalysis for the Homogeneous Hydrogenation of CO2to MethanolJournal of the American Chemical Society2011528