| 1 | Hirshfeld surface analysis | CrystEngComm | 2009 | 7,224 |
| 2 | Fingerprinting intermolecular interactions in molecular crystals | CrystEngComm | 2002 | 3,790 |
| 3 | CH/? hydrogen bonds in crystals | CrystEngComm | 2004 | 1,416 |
| 4 | Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database | CrystEngComm | 2004 | 1,131 |
| 5 | B3LYP augmented with an empirical dispersion term (B3LYP-D*) as applied to molecular crystals | CrystEngComm | 2008 | 874 |
| 6 | Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology | CrystEngComm | 2010 | 745 |
| 7 | Recent advances in crystal engineering | CrystEngComm | 2010 | 729 |
| 8 | Building co-crystals with molecular sense and supramolecular sensibility | CrystEngComm | 2005 | 713 |
| 9 | Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database | CrystEngComm | 2011 | 694 |
| 10 | Topology of interpenetration | CrystEngComm | 2001 | 667 |
| 11 | Fundamental growth principles of colloidal metal nanoparticles – a new perspective | CrystEngComm | 2015 | 625 |
| 12 | Acid–base crystalline complexes and the pKa rule | CrystEngComm | 2012 | 606 |
| 13 | Water clusters in organic molecular crystals | CrystEngComm | 2002 | 605 |
| 14 | Solvent-free synthesis of a microporous metal–organic framework | CrystEngComm | 2006 | 603 |
| 15 | Layered organic–inorganic hybrid perovskites: structure, optical properties, film preparation, patterning and templating engineering | CrystEngComm | 2010 | 597 |
| 16 | The role of solvent in mechanochemical and sonochemical cocrystal formation: a solubility-based approach for predicting cocrystallisation outcome | CrystEngComm | 2009 | 589 |
| 17 | Comparing entire crystal structures: structural genetic fingerprinting | CrystEngComm | 2007 | 581 |
| 18 | Visualisation and characterisation of voids in crystalline materials | CrystEngComm | 2011 | 577 |
| 19 | Bulk crystal growth of hybrid perovskite material CH3NH3PbI3 | CrystEngComm | 2015 | 555 |
| 20 | Lone pair–π interactions: a new supramolecular bond? | CrystEngComm | 2008 | 552 |
| 21 | Formation of high crystalline ZIF-8 in an aqueous solution | CrystEngComm | 2013 | 544 |
| 22 | CH/π hydrogen bonds in organic and organometallic chemistry | CrystEngComm | 2009 | 542 |
| 23 | Coordination polymers, metal–organic frameworks and the need for terminology guidelines | CrystEngComm | 2012 | 526 |
| 24 | Metal–organic frameworks as heterogeneous photocatalysts: advantages and challenges | CrystEngComm | 2014 | 480 |
| 25 | Tuning the crystal morphology and size of zeolitic imidazolate framework-8 in aqueous solution by surfactants | CrystEngComm | 2011 | 462 |
| 26 | Controlling ZIF-8 nano- and microcrystal formation and reactivity through zinc salt variations | CrystEngComm | 2014 | 454 |
| 27 | Extended motifs from water and chemical functional groups in organic molecular crystals | CrystEngComm | 2003 | 436 |
| 28 | Mechanochemistry: the varied applications of mechanical bond-breaking | CrystEngComm | 2009 | 421 |
| 29 | New trends in crystal engineering | CrystEngComm | 2005 | 416 |
| 30 | Halogen bonded supramolecular complexes and networks | CrystEngComm | 2008 | 413 |
| 31 | Homo- and heterometallic coordination polymers from the f elements | CrystEngComm | 2007 | 409 |
| 32 | Wet chemical synthesis of metal oxide nanoparticles: a review | CrystEngComm | 2018 | 408 |
| 33 | Static and lattice vibrational energy differences between polymorphs | CrystEngComm | 2015 | 402 |
| 34 | What is a co-crystal? | CrystEngComm | 2007 | 393 |
| 35 | Tape and layer structures in cocrystals of some di- and tricarboxylic acids with 4,4′-bipyridines and isonicotinamide. From binary to ternary cocrystals | CrystEngComm | 2005 | 386 |
| 36 | Borromean links and other non-conventional links in ‘polycatenated’ coordination polymers: re-examination of some puzzling networks | CrystEngComm | 2003 | 364 |
| 37 | Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications | CrystEngComm | 2011 | 357 |
| 38 | Improved visible-light photocatalytic activity of porous carbon self-doped ZnO nanosheet-assembled flowers | CrystEngComm | 2011 | 347 |
| 39 | Screening strategies based on solubility and solution composition generate pharmaceutically acceptable cocrystals of carbamazepine | CrystEngComm | 2008 | 337 |
| 40 | The real structure of ε-Ga2O3 and its relation to κ-phase | CrystEngComm | 2017 | 331 |
| 41 | Structural evolution and characteristics of the phase transformations between α-Fe2O3, Fe3O4 and γ-Fe2O3 nanoparticles under reducing and oxidizing atmospheres | CrystEngComm | 2013 | 328 |
| 42 | Crystal engineering: from weak hydrogen bonds to co-ordination bonds | CrystEngComm | 2003 | 324 |
| 43 | Formate modulated solvothermal synthesis of ZIF-8 investigated using time-resolved in situ X-ray diffraction and scanning electron microscopy | CrystEngComm | 2012 | 323 |
| 44 | Synthesis of graphene–ZnO nanorod nanocomposites with improved photoactivity and anti-photocorrosion | CrystEngComm | 2013 | 321 |
| 45 | Crystal and co-crystal | CrystEngComm | 2003 | 319 |
| 46 | Role of organic fluorine in crystal engineering | CrystEngComm | 2011 | 319 |
| 47 | Combining metals with halogen bonds | CrystEngComm | 2008 | 317 |
| 48 | Discovery, development, and functionalization of Zr(iv)-based metal–organic frameworks | CrystEngComm | 2012 | 311 |
| 49 | Should solid-state molecular packing have to obey the rules of crystallographic symmetry? | CrystEngComm | 2003 | 303 |
| 50 | A comprehensive review on synthesis methods for transition-metal oxide nanostructures | CrystEngComm | 2015 | 303 |
