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Top Articles

#TitleJournalYearPR Citations
1NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic ChemistOrganometallics20103,523
2Facile Synthesis of Silver(I)−Carbene Complexes. Useful Carbene Transfer AgentsOrganometallics19981,059
3[(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexesOrganometallics1992882
4SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric MapsOrganometallics2016796
5New Diphosphine Ligands Based on Heterocyclic Aromatics Inducing Very High Regioselectivity in Rhodium-Catalyzed Hydroformylation: Effect of the Bite AngleOrganometallics1995738
6Neutral Nickel(II)-Based Catalysts for Ethylene PolymerizationOrganometallics1998577
7Comprehensive Organometallic ChemistryOrganometallics1984574
8Palladium-Catalyzed Carbonylation—A Reaction Come of AgeOrganometallics2008566
9Toxicity of Metal Compounds: Knowledge and MythsOrganometallics2017563
10Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] SystemOrganometallics2008513
11Challenges and Opportunities in the Development of Organometallic Anticancer DrugsOrganometallics2012510
12Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to EnonesOrganometallics1997496
13Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation:  Structure and DynamicsOrganometallics2003492
14Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalystOrganometallics1990491
15The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene CatalystsOrganometallics1994487
16Synthesis, Properties, and Hydroboration Activity of the Highly Electrophilic Borane Bis(pentafluorophenyl)borane, HB(C6F5)21Organometallics1998465
17Donor–Acceptor Properties of Ligands from the Natural Orbitals for Chemical ValenceOrganometallics2007464
18Donor-Functionalized Heterocyclic Carbene Complexes of Palladium(II):  Efficient Catalysts for C−C Coupling ReactionsOrganometallics2000457
19Evidence of the formation of zerovalent palladium from Pd(OAc)2 and triphenylphosphineOrganometallics1992455
20Synthesis and Structural Characterization of N-Heterocyclic Carbene Gold(I) ComplexesOrganometallics2005446
21The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)Organometallics2008404
22The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling ReactionsOrganometallics2012397
23A Combined Experimental and Theoretical Study Examining the Binding of N-Heterocyclic Carbenes (NHC) to the Cp*RuCl (Cp* = η5-C5Me5) Moiety:  Insight into Stereoelectronic Differences between Unsaturated and Saturated NHC LigandsOrganometallics2003391
24Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) CatalystsOrganometallics1999390
25A Brief Survey of Our Contribution to Stable Carbene ChemistryOrganometallics2011390
26Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the FutureOrganometallics2019375
27Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine CatalystsOrganometallics1997372
28Heck Reaction in Ionic Liquids and the in Situ Identification ofN-Heterocyclic Carbene Complexes of PalladiumOrganometallics2000370
29Homoleptic carbene-silver(I) and carbene-copper(I) complexesOrganometallics1993363
30Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small MoleculesOrganometallics2011360
31Dibenzo[a,e]cyclooctatetraene in a proposed test for heterogeneity in catalysts formed from soluble platinum-group metal complexesOrganometallics1983354
32Synthesis, Luminescence, Electrochemistry, and Ion-Binding Studies of Platinum(II) Terpyridyl Acetylide ComplexesOrganometallics2001353
33Group 11 Metal Complexes of N-Heterocyclic Carbene Ligands:  Nature of the MetalCarbene BondOrganometallics2004352
34Organometallic Single-Molecule MagnetsOrganometallics2014349
35Zerovalent Palladium and Nickel Complexes of Heterocyclic Carbenes:  Oxidative Addition of Organic Halides, Carbon−Carbon Coupling Processes, and the Heck ReactionOrganometallics1999348
36A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis CatalystsOrganometallics2001342
37Electronic and Steric Parameters of 76 N-Heterocyclic Carbenes in Ni(CO)3(NHC)Organometallics2009342
38The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization CatalystsOrganometallics2010339
39Lewis Acid Properties of Tris(pentafluorophenyl)borane. Structure and Bonding in L−B(C6F5)3Complexes⊥Organometallics1999338
4013C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)Organometallics2009335
41Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium AdductsOrganometallics2013334
42A DFT Study of the Full Catalytic Cycle of the Suzuki−Miyaura Cross-Coupling on a Model SystemOrganometallics2006332
43C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M = Ir, Rh): Regioselectivity, Kinetics, and MechanismOrganometallics2009328
44Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β-Alkylation of Alcohols, and N-Alkylation of AminesOrganometallics2009325
45Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling ReactionsOrganometallics2002324
46Palladium Complexes with Tridentate Pincer Bis-Carbene Ligands as Efficient Catalysts for C−C CouplingOrganometallics2002322
47Suppression of unwanted heterogeneous platinum(0)-catalyzed reactions by poisoning with mercury(0) in systems involving competing homogeneous reactions of soluble organoplatinum compounds: thermal decomposition of bis(triethylphosphine)-3,3,4,4-tetramethylplatinacyclopentaneOrganometallics1985321
48Electrophilic Metal Precursors and a β-Diimine Ligand for Nickel(II)- and Palladium(II)-Catalyzed Ethylene PolymerizationOrganometallics1997321
49Synthesis of Well-DefinedN-Heterocyclic Carbene Silver(I) ComplexesOrganometallics2005315
50A Ruthenium(II) Complex with aC2-Symmetric Diphosphine/Diamine Tetradentate Ligand for Asymmetric Transfer Hydrogenation of Aromatic Ketones†Organometallics1996311