Organic Chemistry Frontiers

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#	Title	Journal	Year	Citations
1	Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups	Organic Chemistry Frontiers	2015	1,379
2	Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups	Organic Chemistry Frontiers	2014	519
3	Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations	Organic Chemistry Frontiers	2015	389
4	Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis	Organic Chemistry Frontiers	2014	370
5	Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation	Organic Chemistry Frontiers	2017	316
6	Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds	Organic Chemistry Frontiers	2018	270
7	Conquering three-carbon axial chirality of allenes	Organic Chemistry Frontiers	2014	258
8	Iron-catalyzed/mediated oxidative transformation of C–H bonds	Organic Chemistry Frontiers	2014	253
9	Direct activation of relatively unstrained carbon–carbon bonds in homogeneous systems	Organic Chemistry Frontiers	2014	240
10	Progress in the synthesis of perylene bisimide dyes	Organic Chemistry Frontiers	2019	238
11	Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds	Organic Chemistry Frontiers	2016	230
12	Pyridinium salts: from synthesis to reactivity and applications	Organic Chemistry Frontiers	2018	230
13	Recent advances in photoinduced trifluoromethylation and difluoroalkylation	Organic Chemistry Frontiers	2016	228
14	Neglected sulfur(vi) pharmacophores in drug discovery: exploration of novel chemical space by the interplay of drug design and method development	Organic Chemistry Frontiers	2019	202
15	Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis	Organic Chemistry Frontiers	2018	201
16	The Mitsunobu reaction in the 21^st century	Organic Chemistry Frontiers	2015	197
17	Recent developments in 1,6-addition reactions of para-quinone methides (p-QMs)	Organic Chemistry Frontiers	2020	195
18	Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates	Organic Chemistry Frontiers	2014	179
19	Progresses in organocatalytic asymmetric dearomatization reactions of indole derivatives	Organic Chemistry Frontiers	2020	175
20	A remarkable solvent effect of fluorinated alcohols on transition metal catalysed C–H functionalizations	Organic Chemistry Frontiers	2016	172
21	Stereoselective synthesis and applications of spirocyclic oxindoles	Organic Chemistry Frontiers	2021	165
22	Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp³)–H bond activation	Organic Chemistry Frontiers	2015	161
23	Recent progress in selenium-catalyzed organic reactions	Organic Chemistry Frontiers	2019	159
24	Recent advances in multi-component reactions and their mechanistic insights: a triennium review	Organic Chemistry Frontiers	2021	158
25	Photoredox sheds new light on nickel catalysis: from carbon–carbon to carbon–heteroatom bond formation	Organic Chemistry Frontiers	2016	156
26	Catalytic enantioselective organic transformations via visible light photocatalysis	Organic Chemistry Frontiers	2015	155
27	Lu's [3 + 2] cycloaddition of allenes with electrophiles: discovery, development and synthetic application	Organic Chemistry Frontiers	2017	155
28	New entries toward the synthesis of OCF₃-containing molecules	Organic Chemistry Frontiers	2016	152
29	Sonogashira coupling in natural product synthesis	Organic Chemistry Frontiers	2014	150
30	Catalytic C–H amination at its limits: challenges and solutions	Organic Chemistry Frontiers	2017	146
31	Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation	Organic Chemistry Frontiers	2018	145
32	Copper-mediated difluoromethylation of electron-poor aryl iodides at room temperature	Organic Chemistry Frontiers	2014	143
33	Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process	Organic Chemistry Frontiers	2018	135
34	Recent advances in the total synthesis of cyclobutane-containing natural products	Organic Chemistry Frontiers	2020	129
35	Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes	Organic Chemistry Frontiers	2014	126
36	Copper-catalyzed oxidative ipso-carboalkylation of activated alkynes with ethers leading to 3-etherified azaspiro[4.5]trienones	Organic Chemistry Frontiers	2014	126
37	Exploring and elaborating the novel excited state dynamical behavior of a bisflavonol system	Organic Chemistry Frontiers	2018	126
38	Recent advance in the C–F bond functionalization of trifluoromethyl-containing compounds	Organic Chemistry Frontiers	2021	122
39	Recent advances in organocatalytic asymmetric multicomponent cascade reactions for enantioselective synthesis of spirooxindoles	Organic Chemistry Frontiers	2021	122
40	Recent advances in the synthesis of indoles from alkynes and nitrogen sources	Organic Chemistry Frontiers	2020	120
41	Recent advances in tandem selenocyclization and tellurocyclization with alkenes and alkynes	Organic Chemistry Frontiers	2020	118
42	Catalysis by electrons and holes: formal potential scales and preparative organic electrochemistry	Organic Chemistry Frontiers	2015	117
43	Transition-metal-free direct C-3 alkylation of quinoxalin-2(1H)-ones with ethers	Organic Chemistry Frontiers	2018	117
44	Modern multicomponent reactions for better drug syntheses	Organic Chemistry Frontiers	2014	116
45	Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide	Organic Chemistry Frontiers	2018	116
46	Recent advances in transition metal-catalyzed olefinic C–H functionalization	Organic Chemistry Frontiers	2021	116
47	Recent advances in transition metal-catalysed hydroacylation of alkenes and alkynes	Organic Chemistry Frontiers	2016	112
48	Merging photochemistry with electrochemistry in organic synthesis	Organic Chemistry Frontiers	2020	111
49	Electrochemical Minisci-type trifluoromethylation of electron-deficient heterocycles mediated by bromide ions	Organic Chemistry Frontiers	2019	108
50	Copper-catalyzed trifluoromethylthiolation of aryl and vinyl boronic acids with a shelf-stable electrophilic trifluoromethylthiolating reagent	Organic Chemistry Frontiers	2014	107

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