Consequences of kinetic inhomogeneities in glasses

Donna N. Perera and Peter Harrowell
Phys. Rev. E 54, 1652 – Published 1 August 1996
PDFExport Citation

Abstract

Many of the physical pictures used to rationalize the phenomenology of glassy dynamics rest upon a consideration of spatial fluctuations in the relaxation kinetics of the glass-forming liquid. We examine the wide ranging consequences which flow from assuming the existence of transient kinetic inhomogeneities. These consequences include: strong and fragile behavior, two-step relaxation processes, nonlinear relaxation following temperature jumps, spatially correlated kinetics and non-Gaussian behavior of incoherent processes. These general predictions are explored in simulations in which relaxation is governed by diffusing defects. © 1996 The American Physical Society.

  • Received 14 December 1995

DOI:https://doi.org/10.1103/PhysRevE.54.1652

©1996 American Physical Society

Authors & Affiliations

Donna N. Perera and Peter Harrowell

  • School of Chemistry, University of Sydney, New South Wales 2006, Australia

References (Subscription Required)

Click to Expand
Issue

Vol. 54, Iss. 2 — August 1996

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×