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Stabilization of Magnetite Nanoparticles in Humic Acid Medium and Study of Their Sorption Properties

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Abstract

The formation kinetics of magnetite nanoparticles upon their stabilization with potassium humate (PH) has been studied. It has been shown that the properties of Fe3O4/PH composite particles depend essentially on the time interval between the onset of nucleation and the moment of PH addition, as well as on PH concentration during the synthesis. It has been found that the introduction of PH in the optimum concentration gives rise to the formation of a protective adsorption layer, which provides magnetic particles with resistance to aggregation and sedimentation. The study of the sorption properties of magnetic Fe3O4/PH particles with respect to an antibiotic, ciprofloxacin, as depending on the synthesis conditions and characteristics of the particles has shown that the composite particles remove the antibiotic from aqueous solutions much more efficiently than do the unmodified magnetite particles.

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ACKNOWLEDGMENTS

We are very grateful to Cand. Chem. A.V. Sybachin (Department of Macromolecular Compounds, Moscow State University) for help in studying colloid properties of nanoparticles.

Funding

This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-01270/18 and 17-43-500631 and performed within the framework of a state order to the Institute of Problems of Chemical Physics, Russian Academy of Sciences (0089-2019-0008). Sorption properties of materials with respect to ciprofloxacin were studied within the framework of a state order to the Institute of Chemistry, Far East Branch, Russian Academy of Sciences (265-2019-0002).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    G. I. Dzhardimalieva & V. I. Irzhak

  2. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    S. Yu. Bratskaya, V. Yu. Maiorov & Yu. O. Privar

  3. Eltsin Kyrgyz-Russian Slavic University, 720000, Bishkek, Kyrgyz Republic

    E. D. Kasymova

  4. Moscow Aviation Institute, 125993, Moscow, Russia

    G. I. Dzhardimalieva, L. S. Kulyabko & K. A. Kydralieva

  5. Institute of Chemistry and Phytotechnologies, National Academy of Sciences of Kyrgyz Republic, 720071, Bishkek, Kyrgyz Republic

    Sh. Zh. Zhorobekova

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  1. G. I. Dzhardimalieva
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  2. V. I. Irzhak
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  3. S. Yu. Bratskaya
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  4. V. Yu. Maiorov
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  5. Yu. O. Privar
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  6. E. D. Kasymova
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  7. L. S. Kulyabko
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  8. Sh. Zh. Zhorobekova
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  9. K. A. Kydralieva
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Correspondence to G. I. Dzhardimalieva.

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Translated by L. Tkachenko

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Dzhardimalieva, G.I., Irzhak, V.I., Bratskaya, S.Y. et al. Stabilization of Magnetite Nanoparticles in Humic Acid Medium and Study of Their Sorption Properties. Colloid J 82, 1–7 (2020). https://doi.org/10.1134/S1061933X20010032

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  • DOI: https://doi.org/10.1134/S1061933X20010032

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