Reactions of [H2N(CH2)3]8Si8O12 or its octahydrochloride salt with a variety of electrophiles, including anhydrides, lactones, acid chlorides, α,β-unsaturated esters and isocyanates, afforded functionalized R8Si8O12 frameworks in good to excellent yields. Practical methods for the synthesis of [HO(CH2)3]8Si8O12, [OCN(CH2)3]8Si8O12 and [(Ph2PCH2)2N(CH2)3]8Si8O12 are also reported.
F. J. Feher, K. D. Wyndham, D. Soulivong and F. Nguyen, J. Chem. Soc., Dalton Trans., 1999, 1491 DOI: 10.1039/A807302C
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