Aryl-lead triacetates react readily with sodium azide in dimethyl sulphoxide at room temperature to give aryl azides in high yield. By employing aryl-lead triacetates, generated in situ from arylboronic acids, this new reaction provides a two-step route from aryl halides to aryl azides.
M. Huber and J. T. Pinhey, J. Chem. Soc., Perkin Trans. 1, 1990, 721 DOI: 10.1039/P19900000721
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