Issue 42, 2009
From the journal:

Chemical Communications

A supramolecular Cu(ii) metallocyclophane probe for guanosine 5′-monophosphate†

Akhil K. Nair,a   Prakash P. Neelakandana  and  Danaboyina Ramaiah*a  

* Corresponding authors

a Photosciences and Photonics, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST), CSIR, Trivandrum 695 019, India
E-mail: rama@csrrltrd.res.nic.in
Fax: +91 471 2491712
Tel: +91 471 2515362

Abstract

We demonstrate Cu2+ ion induced formation of a novel water soluble metallocyclophane [1·CuCl2]2, which uniquely recognizes guanosine 5′-monophosphate through changes in emission intensity utilizing synergistic effects of electrostatic, coordinative and π-stacking interactions inside the cavity.

Graphical abstract: A supramolecular Cu(ii) metallocyclophane probe for guanosine 5′-monophosphate

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Article information

DOI
https://doi.org/10.1039/B911855A
Article type
Communication
Submitted
17 Jun 2009
Accepted
03 Aug 2009
First published
17 Aug 2009

Chem. Commun., 2009, 6352-6354

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A supramolecular Cu(II) metallocyclophane probe for guanosine 5′-monophosphate

A. K. Nair, P. P. Neelakandan and D. Ramaiah, Chem. Commun., 2009, 6352 DOI: 10.1039/B911855A

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