| 1 | A homochiral Nickel(II) complex [Ni(P'N)2]Cl2: Synthesis, characterization, crystal structure, luminescence, DFT and Hirshfeld surface studies | 4.1 | 2 | Citations (PDF) |
| 2 | Synthesis, crystal structure and computational studies of a new cationic manganese complex with a N-(2-(diisopropylphosphinyl)ethyl)quinolin-8-amine ligand | 4.1 | 0 | Citations (PDF) |
| 3 | Reactivity umpolung (reversal) of ligands in transition metal complexes | 37.7 | 14 | Citations (PDF) |
| 4 | Synthesis of N-Heterocyclic Carbene Complexes by Oxidative Addition of 4-Iodo-imidazolium Salts Followed by an Unusual Rearrangement | 2.9 | 3 | Citations (PDF) |
| 5 | Mechanochemical Synthesis of Chromium(III) Complexes Containing Bidentate PN and Tridentate P-NH-P and P-NH-P′ Ligands | 4.3 | 3 | Citations (PDF) |
| 6 | Insights into the chemistry of Kubas’ chromium dihydrogen complexes | 2.8 | 3 | Citations (PDF) |
| 7 | Relationship between Transition-Metal Hydride Bond Lengths and Stretching Wavenumbers | 4.6 | 6 | Citations (PDF) |
| 8 | Trans Ligand Determines the Stability of Paramagnetic Manganese(II) Hydrides of the Type trans-[MnH(L)(dmpe)2]+ Where L is PMe3, C2H4, or CO | 4.6 | 6 | Citations (PDF) |
| 9 | Electronic insights into aminoquinoline-based PNHN ligands: protonation state dictates geometry while coordination environment dictates N–H acidity and bond strength | 3.0 | 1 | Citations (PDF) |
| 10 | Osmium(II)-Induced Rearrangement of Allenols for Metallafuran Complexes | 2.9 | 7 | Citations (PDF) |
| 11 | A Ruthenium Protic N-Heterocyclic Carbene Complex as a Precatalyst for the Efficient Transfer Hydrogenation of Aryl Ketones | 2.9 | 16 | Citations (PDF) |
| 12 | Density Functional Theory Study on the Selective Reductive Amination of Aldehydes and Ketones over Their Reductions to Alcohols Using Sodium Triacetoxyborohydride | 4.3 | 6 | Citations (PDF) |
| 13 | A Plausible Mechanism for the Iridium-Catalyzed Hydrogenation of a Bulky N-Aryl Imine in the (S)-Metolachlor Process | 4.2 | 4 | Citations (PDF) |
| 14 | Electrochemistry of transition metal hydride diphosphine complexes trans-MH(X)(PP)2 and trans-[MH(L)(PP)2]+, M = Fe, Ru, Os; PP = chelating phosphine ligand | 2.8 | 6 | Citations (PDF) |
| 15 | Enantioselective direct, base-free hydrogenation of ketones by a manganese amido complex of a homochiral, unsymmetrical P–N–P′ ligand | 4.0 | 45 | Citations (PDF) |
| 16 | Tridentate NPN Ligands with a Central Secondary Phosphine Oxide Donor and their Corresponding Metal Complexes | 0.9 | 1 | Citations (PDF) |
| 17 | Trans Element-Hydrogen Bonds: A Distinctive Difference Between Transition Metals and Main Group Elements | 4.6 | 1 | Citations (PDF) |
| 18 | Mechanistic Similarities and Differences for Hydrogenation of Aromatic Heterocycles and Aliphatic Carbonyls on Sulfided Ru Nanoparticles | 12.4 | 9 | Citations (PDF) |
| 19 | A One-Step Preparation of Tetradentate Ligands with Nitrogen and Phosphorus Donors by Reductive Amination and Representative Iron Complexes | 4.6 | 7 | Citations (PDF) |
| 20 | Using nature’s blueprint to expand catalysis with Earth-abundant metals | 36.2 | 506 | Citations (PDF) |
| 21 | Systematic Trends in the Electrochemical Properties of Transition Metal Hydride Complexes Discovered by Using the Ligand Acidity Constant Equation | 15.0 | 14 | Citations (PDF) |
| 22 | Crystal structure of bis[(R,R)-1,2-(binaphthylphosphonito)ethane]dichloridoiron(II) dichloromethane disolvate | 0.5 | 1 | Citations (PDF) |
| 23 | Fundamentals and applications of photocatalytic CO2 methanation | 13.7 | 452 | Citations (PDF) |
| 24 | Metal Hydride Vibrations: The Trans Effect of the Hydride | 4.6 | 16 | Citations (PDF) |
| 25 | Enantioselective Hydrogenation of Activated Aryl Imines Catalyzed by an Iron(II) P-NH-P′ Complex | 3.5 | 46 | Citations (PDF) |
| 26 | Non-Contact Universal Sample Presentation for Room Temperature Macromolecular Crystallography Using Acoustic Levitation | 3.4 | 23 | Citations (PDF) |
| 27 | PNN′ & P<sub>2</sub>NN′ ligands<i>via</i>reductive amination with phosphine aldehydes: synthesis and base-metal coordination chemistry | 3.0 | 18 | Citations (PDF) |
| 28 | Phosphine-free ruthenium NCN-ligand complexes and their use in catalytic CO<sub>2</sub> hydrogenation | 3.0 | 13 | Citations (PDF) |
| 29 | Physical insights into mechanistic processes in organometallic chemistry: an introduction | 3.0 | 4 | Citations (PDF) |
| 30 | Catalytic Homogeneous Asymmetric Hydrogenation: Successes and Opportunities | 2.9 | 265 | Citations (PDF) |
| 31 | DFT methods applied to answer the question: how accurate is the ligand acidity constant method for estimating the pKa of transition metal hydride complexes MHXL4 when X is varied? | 3.0 | 13 | Citations (PDF) |
| 32 | Iridium and Rhodium Complexes Containing Enantiopure Primary Amine-Tethered N-Heterocyclic Carbenes: Synthesis, Characterization, Reactivity, and Catalytic Asymmetric Hydrogenation of Ketones | 2.9 | 24 | Citations (PDF) |
| 33 | Asymmetric Transfer Hydrogenation of Ketones with Well-Defined Manganese(I) PNN and PNNP Complexes | 2.9 | 107 | Citations (PDF) |
| 34 | Estimating the Wavenumber of Terminal Metal-Hydride Stretching Vibrations of Octahedral d<sup>6</sup> Transition Metal Complexes | 4.6 | 33 | Citations (PDF) |
| 35 | Unsymmetrical Iron P‐NH‐P′ Catalysts for the Asymmetric Pressure Hydrogenation of Aryl Ketones | 3.4 | 86 | Citations (PDF) |
| 36 | Asymmetric Transfer Hydrogenation of Ketones Using New Iron(II) (P‐NH‐N‐P′) Catalysts: Changing the Steric and Electronic Properties at Phosphorus P′ | 2.0 | 26 | Citations (PDF) |
| 37 | Half-Sandwich Ruthenium Catalyst Bearing an Enantiopure Primary Amine Tethered to an N-Heterocyclic Carbene for Ketone Hydrogenation | 12.4 | 27 | Citations (PDF) |
| 38 | A capped trigonal pyramidal molybdenum hydrido complex and an unusually mild sulfur–carbon bond cleavage reaction | 3.4 | 3 | Citations (PDF) |
| 39 | An acoustic on-chip goniometer for room temperature macromolecular crystallography | 5.1 | 1 | Citations (PDF) |
| 40 | From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone | 7.1 | 36 | Citations (PDF) |
| 41 | Ketone Asymmetric Hydrogenation Catalyzed by P-NH-P′ Pincer Iron Catalysts: An Experimental and Computational Study | 12.4 | 87 | Citations (PDF) |
| 42 | Bromidocarbonyl{(1S,2S)-N-[2-(dicyclohexylphosphanyl)ethylidenyl]-N′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate | 0.3 | 3 | Citations (PDF) |
| 43 | Insights into metal–ligand hydrogen transfer: a square-planar ruthenate complex supported by a tetradentate amino–amido-diolefin ligand | 3.4 | 6 | Citations (PDF) |
| 44 | Density Functional Theory Calculations Support the Additive Nature of Ligand Contributions to the pKa of Iron Hydride Phosphine Carbonyl Complexes | 4.6 | 13 | Citations (PDF) |
| 45 | Aqueous biphasic iron-catalyzed asymmetric transfer hydrogenation of aromatic ketones | 4.4 | 23 | Citations (PDF) |
| 46 | Iron Group Hydrides in Noyori Bifunctional Catalysis | 6.7 | 37 | Citations (PDF) |
| 47 | Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes | 52.6 | 228 | Citations (PDF) |
| 48 | Exploring the decomposition pathways of iron asymmetric transfer hydrogenation catalysts | 3.0 | 18 | Citations (PDF) |
| 49 | Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts | 17.0 | 417 | Citations (PDF) |
| 50 | An Unsymmetrical Iron Catalyst for the Asymmetric Transfer Hydrogenation of Ketones | 2.3 | 38 | Citations (PDF) |
| 51 | {N,N′-Bis[2-(diphenylphosphanyl)ethan-1-ylidene]ethylenediamine}bromido(p-toluenesulfonylmethyl isocyanide)iron(II) tetraphenylborate | 0.2 | 2 | Citations (PDF) |
| 52 | Iron(II) Complexes Containing Unsymmetrical P–N–P′ Pincer Ligands for the Catalytic Asymmetric Hydrogenation of Ketones and Imines | 15.0 | 300 | Citations (PDF) |
| 53 | Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants | 15.0 | 116 | Citations (PDF) |
| 54 | A sulfur mimic of 1,1-bis(diphenylphosphino)methane: a new ligand opens up | 3.4 | 14 | Citations (PDF) |
| 55 | Ligand-based molecular recognition and dioxygen splitting: an endo epoxide ending | 3.0 | 4 | Citations (PDF) |
| 56 | Reactivity of Ruthenium Phosphido Species Generated through the Deprotonation of a Tripodal Phosphine Ligand and Implications for Hydrophosphination | 15.0 | 33 | Citations (PDF) |
| 57 | Intramolecular CH/OH Bond Cleavage with Water and Alcohol Using a Phosphine‐Free Ruthenium Carbene NCN Pincer Complex | 3.4 | 22 | Citations (PDF) |
| 58 | Oxidative Kinetic Resolution of Aromatic Alcohols Using Iron Nanoparticles | 2.5 | 4 | Citations (PDF) |
| 59 | Structural properties of trans hydrido–hydroxo M(H)(OH)(NH2CMe2CMe2NH2)(PPh3)2 (M = Ru, Os) complexes and their proton exchange behaviour with water in solution | 3.0 | 18 | Citations (PDF) |
| 60 | Synthesis of New Late Transition Metal P,P-, P,N-, and P,O- Complexes Using Phosphonium Dimers as Convenient Ligand Precursors | 4.6 | 17 | Citations (PDF) |
| 61 | Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation | 52.6 | 2,098 | Citations (PDF) |
| 62 | The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key | 15.0 | 183 | Citations (PDF) |
| 63 | Synthesis, Characterization, and Activity of Yttrium(III) Nitrate Complexes Bearing Tripodal Phosphine Oxide and Mixed Phosphine–Phosphine Oxide Ligands | 4.6 | 30 | Citations (PDF) |
| 64 | Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand | 4.8 | 122 | Citations (PDF) |
| 65 | Symmetry Aspects of H2 Splitting by Five-Coordinate d6 Ruthenium Amides, and Calculations on Acetophenone Hydrogenation, Ruthenium Alkoxide Formation, and Subsequent Hydrogenolysis in a Model trans-Ru(H)2(diamine)(diphosphine) System | 4.6 | 49 | Citations (PDF) |
| 66 | Effect of chelating ring size in catalytic ketone hydrogenation: facile synthesis of ruthenium(ii) precatalysts containing an N-heterocyclic carbene with a primary amine donor for ketone hydrogenation and a DFT study of mechanisms | 3.0 | 65 | Citations (PDF) |
| 67 | Iron Nanoparticles Catalyzing the Asymmetric Transfer Hydrogenation of Ketones | 15.0 | 235 | Citations (PDF) |
| 68 | From amine to ruthenaziridine to azaallyl: unusual transformation of di-(2-pyridylmethyl)amine on ruthenium | 3.0 | 6 | Citations (PDF) |
| 69 | Low-Valent Ene–Amido Iron Complexes for the Asymmetric Transfer Hydrogenation of Acetophenone without Base | 15.0 | 161 | Citations (PDF) |
| 70 | (η5-Pentamethylcyclopentadienyl)(η6-toluene)ruthenium(II) hexafluoridophosphate | 0.2 | 1 | Citations (PDF) |
| 71 | Template Synthesis of Iron(II) Complexes Containing Tridentate P−N−S, P−N−P, P−N−N, and Tetradentate P−N−N−P Ligands | 4.6 | 43 | Citations (PDF) |
| 72 | Iron Complexes for the Catalytic Transfer Hydrogenation of Acetophenone: Steric and Electronic Effects Imposed by Alkyl Substituents at Phosphorus | 4.6 | 89 | Citations (PDF) |
| 73 | Effect of the Structure of the Diamine Backbone of P−N−N−P ligands in Iron(II) Complexes on Catalytic Activity in the Transfer Hydrogenation of Acetophenone | 4.6 | 97 | Citations (PDF) |
| 74 | The hydrogenation of molecules with polar bonds catalyzed by a ruthenium(ii) complex bearing a chelating N-heterocyclic carbene with a primary amine donor | 3.4 | 125 | Citations (PDF) |
| 75 | A DFT investigation into the origin of regioselectivity in palladium-catalyzed allylic amination | 1.7 | 17 | Citations (PDF) |
| 76 | Iron(II) Complexes for the Efficient Catalytic Asymmetric Transfer Hydrogenation of Ketones | 3.4 | 183 | Citations (PDF) |
| 77 | Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes | 37.7 | 733 | Citations (PDF) |
| 78 | Kinetic Hydrogen/Deuterium Effects in the Direct Hydrogenation of Ketones Catalyzed by a Well-Defined Ruthenium Diphosphine Diamine Complex | 15.0 | 107 | Citations (PDF) |
| 79 | Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis | 15.0 | 274 | Citations (PDF) |
| 80 | Synthesis and Characterization of Iron(II) Complexes with Tetradentate Diiminodiphosphine or Diaminodiphosphine Ligands as Precatalysts for the Hydrogenation of Acetophenone | 4.6 | 134 | Citations (PDF) |
| 81 | Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds | 14.4 | 346 | Citations (PDF) |
| 82 | Template Syntheses of Iron(II) Complexes Containing Chiral P−N−N−P and P−N−N Ligands | 4.6 | 56 | Citations (PDF) |
| 83 | Properties of the Polyhydride Anions [WH5(PMe2Ph)3]-and [ReH4(PMePh2)3]-and Periodic Trends in the Acidity of Polyhydride Complexes | 4.6 | 19 | Citations (PDF) |
| 84 | Novel hydrido-ruthenium(ii) complexes with histidine derivatives and their application in the hydrogenation of ketones | 3.0 | 11 | Citations (PDF) |
| 85 | An Acidity Scale of Tetrafluoroborate Salts of Phosphonium and Iron Hydride Compounds in [D2]Dichloromethane | 3.4 | 32 | Citations (PDF) |
| 86 | An acidity scale of phosphonium tetraphenylborate salts and ruthenium dihydrogen complexes in dichloromethane | 1.7 | 20 | Citations (PDF) |
| 87 | Synthesis of Ruthenium Hydride Complexes Containing beta-Aminophosphine Ligands Derived from Amino Acids and their use in the H2-Hydrogenation of Ketones and Imines | 3.8 | 101 | Citations (PDF) |
| 88 | A modular design of ruthenium catalysts with diamine and BINOL-derived phosphinite ligands that are enantiomerically-matched for the effective asymmetric transfer hydrogenation of simple ketones | 3.4 | 49 | Citations (PDF) |
| 89 | Enantioselective Tandem Michael Addition/H2-Hydrogenation Catalyzed by Ruthenium Hydride Borohydride Complexes Containing β-aminophosphine Ligands1 | 15.0 | 100 | Citations (PDF) |
| 90 | Applications of Ruthenium Hydride Borohydride Complexes Containing Phosphinite and Diamine Ligands to Asymmetric Catalytic Reactions | 4.8 | 97 | Citations (PDF) |
| 91 | Chemistry of Ruthenium(II) Monohydride and Dihydride Complexes Containing Pyridyl Donor Ligands Including Catalytic Ketone H2-Hydrogenation1 | 4.6 | 51 | Citations (PDF) |
| 92 | A Succession of Isomers of Ruthenium Dihydride Complexes. Which One Is the Ketone Hydrogenation Catalyst? | 15.0 | 170 | Citations (PDF) |
| 93 | Hydrogenation versus Transfer Hydrogenation of Ketones: Two Established Ruthenium Systems Catalyze Both | 3.4 | 213 | Citations (PDF) |
| 94 | Mechanism of the Hydrogenation of Ketones Catalyzed bytrans-Dihydrido(diamine)ruthenium(II) Complexes† | 15.0 | 510 | Citations (PDF) |
| 95 | Large Effects of Ion Pairing and Protonic−Hydridic Bonding on the Stereochemistry and Basicity of Crown-, Azacrown-, and Cryptand-222-potassium Salts of Anionic Tetrahydride Complexes of Iridium(III) | 4.6 | 38 | Citations (PDF) |
| 96 | Catalytic Cycle for the Asymmetric Hydrogenation of Prochiral Ketones to Chiral Alcohols: Direct Hydride and Proton Transfer from Chiral Catalyststrans-Ru(H)2(diphosphine)(diamine) to Ketones and Direct Addition of Dihydrogen to the Resulting Hydridoamido Complexes | 15.0 | 292 | Citations (PDF) |
| 97 | [{ReH2(PMePh2)2}2(μ-H)3]-: The First Member of a New Class of Anionic Polyhydride Dimers [Re2H7L4]- | 4.6 | 18 | Citations (PDF) |
| 98 | Intra- and inter-ion-pair protonic-hydridic bonding in polyhydridobis(phosphine)rhenates | 1.7 | 17 | Citations (PDF) |
| 99 | The effect of ancillary ligands on intramolecular protonhydride (NH⋯HIr) bonding in complexes of iridium(III) | 2.1 | 13 | Citations (PDF) |
| 100 | Probing the motion of the η2-dideuterium ligand by solution and solid-state 2H NMR spectroscopy | 1.7 | 19 | Citations (PDF) |
| 101 | Monohydride complexes of W (IV) containing bulky selenolate ligands: X-ray crystal structure determination of [WH(SeC6H3Pri2-2,6)3(PMe2Ph)2] | 2.8 | 10 | Citations (PDF) |
| 102 | Bis[1,2-bis(diphenylphosphino)ethane-P,P']chloroosmium(II) Hexafluorophosphate Dichloromethane Solvate | 0.4 | 2 | Citations (PDF) |
| 103 | The effect of deuteration on the stabilities of cis-polyacetylene and polystyrene | 4.1 | 5 | Citations (PDF) |
| 104 | New dihydrogen complexes: the synthesis and spectroscopic properties of iron(II), ruthenium(II), and osmium(II) complexes containing the meso-tetraphos-1 ligand | 1.7 | 33 | Citations (PDF) |
| 105 | Additions and Corrections - π-Bonding of the Dihydrogen Ligand Probed by Mossbauer Spectroscopy. | 4.6 | 0 | Citations (PDF) |
| 106 | Structure of dimethyl(phenyl)phosphonium tris(1,2-benzenedithiolato)tungsten(V) | 0.4 | 16 | Citations (PDF) |
| 107 | Structure of trans-[OsH(η2-H2)(PPh2CH2CH2PPh2)2][BF4] | 0.4 | 4 | Citations (PDF) |
| 108 | Molybdenum complexes containing hydride and sulphur donor ligands. | 3.0 | 2 | Citations (PDF) |
| 109 | Bis[1,2-bis(diethylphosphino)ethane](η2-dihydrogen)hydridoosmium(II) tetraphenylborate | 0.4 | 1 | Citations (PDF) |
| 110 | Monoclinic and triclinic forms of [1,2-bis(diphenylphosphino)propane](η6-methyldiphenylphosphine)(methyldiphenylphosphine)molybdenum(0) benzene solvate | 0.4 | 4 | Citations (PDF) |
| 111 | NMR Studies of the Complexes trans-[M(η2-H2)(H)(Ph2PCH2CH2PEt2)2]X (M=Fe, X = BPh4; M = Os, X = BF4): Evidence for Unexpected Shortening of the H-H Bond | 4.6 | 24 | Citations (PDF) |
| 112 | trans-Bis(dinitrogen)tetrakis(methyldiphenylphosphine)molybdenum(0) benzene solvate, [Mo(N2)2{P(CH3)(C6H5)2}4].1.5(C6H6) | 0.4 | 2 | Citations (PDF) |
| 113 | Radiation chemistry of acetylene at high intensity: the initial product distributions | 1.7 | 9 | Citations (PDF) |
| 114 | Paramagnetic Transition Metal Hydride Complexes | 52.6 | 0 | Citations (PDF) |
